21. Evan Rachel Wood and Marilyn Manson
This is one of those really interesting couples that would make you do a double take on the street. Anyway, we all know that Manson never leaves the house without eye liner and lipstick and believe it or not, Wood claims that’s what attracted her to him in the first place. The couple was engaged for a while, but never actually got married. In August 2012, Wood came out as bisexual on Twitter.